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17 Nov 2008 ... Acid and alkaline
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español
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1 2008, 16:42.
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Copper(I) chloride
Unit cell of nantokite
( )
[7758-89-6]
6990000
98.99 /
,
4.140 / 3 ,
430 ° (703 )
1490 ° (1760 ),
0.0062 /100 (20 ° )
( )
sciencelab.com
704
0
3
0
/s : 22, 50, 53 s:22, 60/61
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( 25 °, 100 )
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1
2
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3
4
. , , , , . ( ) . , - - . , :
+ ( 6H5)3 ' [( ( 6H5)3 )] 4
, . , H3O+ 2- . - , S2O3 2- , .. 3 .
.. 3 - [(.. )] 2 . [( 2H2 )]. ( ) . 2 . 1,5- : [1]
Structure of COD complex of CuCl
, 2. [2] ( ).
( ) ' . ( ) - :
+ 2 ' 2
6 + 3/2 2 + 3 2 ' 2 3 2 ( ) 4 + 2
( ) , . .
. [3] , :
(Example Sandmeyer reaction using CuCl)
.
( ) 1,4- , - [4] : [2]
(Addition of RMgX to C=C-C=O mediated by CuCl)
. , ( 3 .. ) " " ( 3)2 , . . ( ) ( ) , ( ) : [2]
(Alkylation of sorbate ester at 4-position mediated by CuCl)
, - . , 1,2- 1,4- (i.e., = ).
( ) ( ) . ().
1. ^ ', . - , , , 1973.
2. ^ a b c , n.n.; , . , 2 ., -, , , 1997.
3. ^ () , . . , 5 ., . 871, , , ', 2003. ( ) , '. , 4 ., . 723, , , 1992.
4. ^ , . s. ; , . . (1941 )." . . ". '. . '. .... 63 : 2308. : 10.1021/ja01854a005 .
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